Oxalic acid

Oxalic acid , also known as (Dicarboxylic Acid or Ethanedioic Acid). It is an organic acid that responds to the general formula C 2 H 2 O 4 .2H 2 O.

Properties

It comes in the form of colorless, odorless crystals with an acidic flavor. Slightly heated effloresce, at 70 o C it becomes anhydrous (without water ), at 100 o C it begins to sublimate, at 160 o C it undergoes igneous fusion and at higher temperatures it decomposes.

It is soluble in 10 parts of water and 2.5 parts of alcohol ; it is poorly soluble in ether . Contact with the skin should be avoided, as it causes irritation.

It is obtained by passing Carbon Monoxide through a hot, concentrated solution of [Sodium hydroxide]] under pressure and then converting the Sodium Formate into Oxalate and converting the latter to acid. Also Sawdust treated with dilute acid or alkali yields a solution containing oxalic acid or the oxalate alkalis.

Its developed structural formula is as follows:

O O – H

\\ /

C – C + 2H 2 O

/ \\

H – O O

Applications

  • In Chemistry:
  • Purifying agent in the manufacture of Glycerin.
  • Obtaining formic acidby reaction with glycerin.
  • Obtaining Estersof Formic Acid.
  • Obtaining pure Dextrin by hydrolysis of the Starch.
  • Purification of Tartaric Acid.
  • Elimination of the last traces of Limein the manufacture of Cream of Tartar and Glycolic Acid.
  • Analytical reagent.
  • Manufacture of intermediate dyes.
  • Stearin purification.
  • Straw bleaching.
  • Coalwashing .
  • Regeneration of colored spark plugs.
  • Metal polish.
  • Urineand Ink Eliminators .
  • Cleaning agent in brewing.
  • Elaboration of blue inks.
  • Photogravure and Lithography.
  • Railroad car cleaner.
  • Anti-chlorine and anti-rust agent in laundry.

 

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